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Исследование деградации флуоресцентных свойств графитоподобного нитрида углерода «Светотехника», 2022, №5

Журнал «Светотехника» №5

Дата публикации 14/10/2022
Страница 59-66

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Исследование деградации флуоресцентных свойств графитоподобного нитрида углерода «Светотехника», 2022, №5
Авторы статьи:
Богомолов Александр Борисович, Зинин Павел Валентинович, Павлов Иван Сергеевич, Галкин Артём Сергеевич, Головин Андрей Леонидович

Богомолов Александр Борисович, инженер. Окончил в 2020 г. РТУ МИРЭА (МИТХТ) по направлению «Стандартизация и метрология»..Аспирант НТЦ УП РАН 3-го года обучения. Область научных интересов: флуоресценцентные материалы

Зинин Павел Валентинович, кандидат физ.-мат. наук. Окончил в 1980 г. физический факультет МГУ. им. М.В. Ломоносова. Ведущий научный сотрудник НТЦ УП РАН. Область научных интересов: углеродные материалы, физика высоких давлений

Павлов Иван Сергеевич, аспирант Института кристаллографии им. А.В. Шубникова. Специалист по просвечивающей микроскопии. Область научных интересов: наноматериалы

Галкин Артём Сергеевич, аспирант ТИСНУМ. Специалист по ИК спектроскопии

Головин Андрей Леонидович, кандидат физ.-мат. наук. Учёный секретарь ФНИЦ «Кристаллография и фотоника» РАН

Аннотация
Графитоподобный нитрид углерода – двумерный флуоресцентный материал с выявленной деградацией флуоресцентных свойств. Он был получен термическим разложением меламина и исследован с помощью ИК спектроскопии, просвечивающей электронной микроскопии и рентгенофазового анализа. Выявлено три основных механизма деградации флуоресценции. Первый и третий – это присоединение водорода к центрам с неподелённой парой электронов, что приводит к критическому изменению флуоресцентных свойств, а второй – адсорбции воды, которая накапливается не только по поверхности материала, но и, возможно, проникает между слоёв, вызывая этим незначительное ухудшение флуоресценции.
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