Light & Engineering 26 (1)

Volume 26
Date of publication 03/30/2018
Pages 105-112

PDF

Phosphors and Fluorescent Converters in Light Sources with Blue LED Crystals. L&E 26 (1) 2018

Articles authors:

Victoriya A. Lapina, Peter P. Pershukevich, Alexei V. Trofimov, Natalya N. Trofimova, Yury B. Tsaplev

Ph.D. Graduated from the Chemistry Faculty of the Kharkiv University in 1975. At present, she is a leader researcher at the Institute of Physics of B.I. Stepanov of the NAN Belarus. Field of scientific interest: nanotechnologies and nanomaterials

Ph.D. Graduated from the Physics Faculty of the BSU in 1973. Senior research associate of the Institute of Physics of B.I. Stepanov of the NAN of Belarus. Field of scientific interest: molecular and atomic physics, spectroscopy

Doctor of Chemistry, graduated from the Faculty of Molecular and Chemical Physics of the MIPT in 1988. At present, he is the Head of a laboratory at the Institute of Biochemical Physics of N.M. Emanuel of the RAS; his fields scientific interest include fluorescence, photochemistry, oxidation stress

Ph.D. Graduated from the Geography-Biological faculty of the MOPI in 1991. At present, she is a senior research associate of the Institute of Biochemical Physics of N.M. Emanuel of the RAS. Field of scientific interest: experimental and theoretical photophysiology

Doctor of Technical Science, senior research associate, graduated from the Physics Faculty of the Moscow State University of M.V. Lomonosov in 1977. He is a leader researcher at the Institute of Biochemical Physics of N.M. Emanuel of the RAS. Field of scientific interest: fluorescence, photochemistry

Abstract

he article presents a review of fluorescent material use: inorganic phosphors, organic polymeric and molecular phosphors, complex (coordination) compounds, quantum dots and frame metal-organic compounds as component materials of fluorescent converters to transform radiation of blue and ultra-violet diode crystals to white light.

References

1. Reference book on lighting engineering / Under the editorship of Yu.B. Aizenberg. The 3rd revised edition, Moscow: Znak, 2006, 972 p.
2. Schubert F. Light emitting diodes / Translation under the editorship of A.E. Yunovich. the 3rd edition, Moscow: Fizmatlit, 2008, 496 p.
3. Fabrikant V.A. Physics, optics, quantum electronics: Selected articles. Moscow: Edition of the Moscow Power Institute, 2000, pp. 96Ц111.
4. Bugrov Physical bases of nitride semiconductor heterostructure optimisation to be used in high-effective LED devices // Thesis work of a Ph.D. St. Petersburg: Physics and technology institute of A.F. Ioffe, 2013.
5. Schlotter P., Schmidt R., Schneider J. Luminescence conversion of blue light emitting diodes // Appl. Phys. A. 1997, Vоl. 64, No. 4, pp. 417Ц418.
6. Hide F., Kozodoy P., DenBaars S.P., Heeger A.J. White light from InGaN/conjugated polymer hybrid light emitting diodes // Appl. Phys. Lett. 1997, Vol. 70, є 20, pp. 2664Ц2666.
7. Nakamura S., Fasol G. The Blue Laser Diode. GaN Based Light Emitters and Lasers. Berlin: Springer-Verlag, 1997?343 p.
8. Schlotter P., Baur J., Hielscher C., Kunzer M., Obloh H., Schmidt R., Schneider J. Fabrication and characterization of GaN/InGaN/AlGaN double heterostructure LEDs and their application in luminescence conversion LEDs // Mat. Sci. Eng. B. 1999, Vol. 59, No. 1, pp. 390Ц394.
9. Soshchin N. P., Bolshukhin VA., Lichmanova V.N. Improvement of production technology of multiligand photophosphors for effective LEDs // Nanoengineering. 2013, #2, pp. 3Ц11.
10. Dwivedi J., Kumar P., Kumar A., Singh V.N., Singh B P., Dhawan S.K., Gupta B.K. A commercial approach for the fabrication of bulk and nano phosphors converted into highly efficient white LEDs // RSC Advances. 2014, Vol. 4. (98), pp. 54936Ц54947.
11. Haranath D., Chander H., Sharma P., Singh S. Enhanced luminescence of Y3Al5O12: Ce3+ nanophosphor for white light emitting diodes // App. Phys. Lett. 2006, Vol. 89, No.173118.
12. McKittrick J., Shea-Rohwer L.E. Review: Down Conversion Materials for Solid-State Lighting // J. Amer. Ceramic Soc. 2014. Vol. 97 (5), pp. 1327Ц1352.
13. Poddenezhnyi E.N., Dobrodei A.O., Boiko A.A., Zdravkov A.V., Grishkova E.I., Khimich N.N. Formation of nanostructured particles of cerium-activated yttrium aluminium garnet by combustion method // Glass Phys. Chem. 2011, Vol. 37 (5), pp. 520Ц523.
14. Naik S.R., Shripathi T., Salker A.V . Preparation, characterization and photoluminescent studies of Cr and Nd co-doped Ce: YAG compounds // Journal of Luminescence. 2015, Vol. 161, pp. 335Ц342.
15. Jia D. Nanophosphors for White Light LEDs // Chem. Eng. Comm. 2007, Vol. 194 (12), pp. 1666Ц1687.
16. Park K.W., Lim S.G., Deressa G., Kim J.S., Kang T.W., Choi H.L., Yu Y.M., Kim Y.S., Ryu J.G., Lee S.H., Kim T.H. High power and temperature luminescence of Y3Al5O12: Ce3+ bulky and pulverized single crystal phosphors by a floating-zone method// Journal of Luminescence. 2015, Vol. 168, pp. 334Ц338.
17. Davydova O. V., Pavlenok A.V., Dobrodey A.O., Poddeneghny E.N., Drobyshevskaya N.E., Alekseenko A.A., Boyko A.A. Features of synthesis of ultradisperse powders of yttrium-aluminum garnet activated by cerium ions using the combustion method // Bulletin of the GSTU of P.O. Sukhoi. 2016, V. 1 (2), pp. 45Ц52.
18. Davydova O. V., Pavlenok A.V., Dobrodey A.O., Poddeneghny E.N., Drobyshevskaya N.E., Boyko A.A., Kravchenko A.I., Savkova T.N. Obtaining and spectral-fluorescent characteristics of composite materials based on YAG: Ce for LED converters // Bulletin of the GSTU of P.O. Sukhoi. 2016, V. 1 (3), pp. 24Ц31.
19. Im W.B., Brinkley S., Hu J., Mikhailovsky A., DenBaars S.P., Seshadri R. Sr2.975-xBaxCe0.025AlO4F: Highly Efficient Green-Emitting Oxyfluoride Phosphor for Solid State White Lighting // Chem. Materials. 2010, Vol. 22, pp. 2842Ц2849.
20. Nyman M., Shea-Rohwer L.E., Martin J.E., Provencio P. Nano-YAG: Ce mechanisms of growth and epoxy-encapsulation // Chem. Materials. 2009. Vol. 21, pp. 1536Ц1542.
21. Briskina Ch. M., Rumyantsev S.I., Ryzhkov M.V., Soshchin N.P., Spassky D.A. Search of optimum compositions of garnet phosphors with Ce3+ for white light emitting diodes // Svetotekhnika. 2012, #5, pp. 37Ц39.
22. Soshchin N. P., Galchina N.A., Kogan L.M., Shirokov S.S., Yunovich A.E. Light emitting diodes of УwarmФ white glow based on p-n heterostructures InGaN/AlGaN/ GaN type covered with phosphors of yttrium-gadolinium garnets // Physics and technology of semiconductors. 2009, V. 43 (5), pp. 700Ц704.
23. Jang H.S., Won Y.-H., Jeon D.Y. Improvement of electroluminescent property of blue LED coated with highly luminescent yellow-emitting phosphors // Appl. Phys. B. 2009, Vol. 95, No. 4, pp. 715Ц720.
24. Kichanov S. E., Frolova E.V., Shevchenko G.P., Kozlenko D.P., Belushkin A.V., Lukin E.V., Malashkevich G.E., Rakhmanov S.K., Glazkov V.P., Savenko B.N. Study of structural features of Y3Al5O12: Ce3+/ Lu2O3 crystalline phosphor when it is forming by the colloidal-and-chemical method // Physics of solid body, 2013, V. 55, #4, pp. 745Ц751.
25. Kawano Y., Kim S.W., Ishigaki T., Uematsu K., Toda K., Takaba H., Sato M. Site engineering concept of Ce3+-activated novel orange-red emission oxide phosphors // Opt. Mat. Express. 2014, Vol. 4, No. 9, pp. 1770Ц1774.
26. Dong X., Zhang J., Zhang L., Zhang X., Hao Z., Luo Y . Yellow?Emitting Sr9Sc(PO4)7: Eu2+, Mn2+ Phosphor with Energy Transfer for Potential Application in White Light Emitting Diodes // Europ. J. Inorg. Chem. 2014, No. 5, pp. 870Ц874.
27. Yang C., Gu G., Zhao X., Liang X., Xiang W. The growth and luminescence properties of Y3Al5O12: Ce3+ single crystal by doping Gd3+ for W-LEDs // Mat. Lett. 2016, Vol. 170, pp. 58Ц61.
28. Chen J., Deng Z., Liu Z., Lin Y., Lan H., Chen D., Fei B., Wang C., Wang F., Hu Q., Cao Y . Optical enhancement brought by doping Gd 3+ ions into Ce: YAG ceramics for indoor white light-emitting diodes // Optics Express. 2015, Vol. 23 (7), pp. A292ЦA298.
29. Shi H., Zhu C., Huang J., Chen J., Chen D., Wang W., Cao Y., Yuan X. Luminescence properties of YAG: Ce, Gd phosphors synthesized under vacuum condition and their white LED performances // Optical Materials Express. 2014, Vol. 4 (4), pp. 649Ц655.
30. Zhu H., Lin C.C., Luo W., Shu S., Liu Z., Liu Y., Kong J., Ma E., Cao Y., Liu R.S., Chen X. Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes // Nature Comm. 2014, Vol. 5, AN. 4312.
31. Zhang C, Heeger A.J. Gallium nitride/conjugated polymer hybrid light emitting diodes: Performance and lifetime // J. Appl. Phys. 1998, V. 84, No. 3, pp. 1579Ц1582.
32. Andersson M.R., Yu G., Heeger A.J. Photoluminescence and electroluminescence of films from soluble PPV-polymers // Synth. Metals. 1997, Vol. 85, pp.1275Ц1276.
33. Huyal I.O., Koldemir U., Ozel T., Demir H.V., Tuncel D. On the origin of high quality white light emission from a hybrid organic/inorganic light emitting diode using azide functionalized polyfluorene // J. Mat. Chem. 2008, Vol. 18, No. 30, pp. 3568Ц-3574.
34. Huyal I.O., Ozel T., Koldemir U., Nizamoglu S., Tuncel D., Demir H.V. White emitting polyfluorene functionalized with azide hybridized on near-UV light emitting diode for high colour rendering index // Optics Express. 2008, Vol. 16, No. 2, pp. 1115Ц1124.
35. Chen K.J., Lai Y.C., Lin B.C., Lin C.C., Chiu S.H., Tu Z.Y., Meng H.F. Efficient hybrid white light-emitting diodes by organic-inorganic materials at different CCT from 3000 K to 9000 K // Optics Express. 2015, Vol. 23, No. 7, pp. A204ЦA210.
36. Ermakov O.N., Kaplunov M.G., Efimov O.N., Yakushchenko I.K., Belov M.Y., Budyka M.F. Hybrid organicЦinorganic light-emitting diodes // Microel. Eng. 2003, Vol. 69, No. 2, pp. 208Ц212.
37. Zhang L., Li B., Lei B., Hong Z., Li W. A triphenylamine derivative as an efficient organic light colour-conversion material for white LEDs // Journal of Luminescence. 2008, Vol. 128, pp. 67Ц73.
38. Kim H.J., Jin J.Y., Lee Y.S., Lee S.H., Hong C.H. An efficient luminescence conversion LED for white light emission, fabricated using a commercial InGaN LED and a 1,8-naphthalimide derivative // Chem. Phys. Lett. 2006, Vol. 431, No. 4, pp. 341Ц345.
39. Jin J.Y., Kim Y.M., Lee S.H., Lee Y.S. Synthesis of an acrylic copolymer bearing fluorescent dye pendants and characterization as a luminescence conversion material in fabrication of a luminescence conversion light-emitting diode // Synth. Metals. 2009, Vol. 159, No. 17, pp.1804Ц1808.
40. Caruso F., Mosca M., Macaluso R., Feltin E., Cali C. Generation of white LED light by frequency downconversion using perylene-based dye // Electron. Lett. 2012, Vol. 48, No. 22, pp.1417Ц1419.
41. Mosca M., Caruso F., Zambito L., Seminara B., Macaluso R., Cali C., Feltin E. Warm white LED light by frequency down-conversion of mixed yellow and red Lumogen // Proc. SPIE. 2013, Vol. 8767, pp. 87670L.
42. Mosca M., Caruso F., Zambito L., Macaluso R., Cali C., Feltin E. Hybrid LEDs Pave Way to New Lighting Applications // Photonics Spectra. 2013, Vol. 47, No. 4, pp. 60Ц64.
43. Caruso F., Mosca M., Rinella S., Macaluso R., Cali C., Saiano F., Feltin E. Frequency-Downconversion Stability of PMMA Coatings in Hybrid White Light-Emitting Diodes // J. Electron. Mat. 2016, Vol. 45, No. 1, pp. 682Ц687.
44. Findlay N.J., Bruckbauer J., Inigo A.R., Breig B., Arumugam S., Wallis D.J., Skabara P.J. An Organic Down-Converting Material for White?Light Emission from Hybrid LEDs // Advanced Mat. 2014, Vol. 26, No. 43, pp. 7290Ц7294.
45. Yue Z., Cheung Y.F., Choi H.W., Zhao Z., Tang B.Z., Wong K.S. Hybrid GaN/Organic white light emitters with aggregation induced emission organic molecule // Optic. Mat. Exp. 2013, Vol. 3, No. 11, pp. 1906Ц1911.
46. Kim S.W., Yoo H.S., Kwon B.H., Kang D.S., Suh M., Jeon D.Y . Organic wavelength converting film based hybrid planar white light emitting diodes // J. Soc. Inform. Display. 2010, Vol. 18, No. 12, pp. 1104Ц1110.
47. Di Martino D., Beverina L., Sassi M., Brovelli S., Tubino R., Meinardi F. Straightforward fabrication of stable white LEDs by embedding of inorganic UVЦLEDs into bulk polymerized polymethyl-methacrylate doped with organic dyes // Sci. Rep. 2014, Vol. 4, No. 4400, pp. 1Ц5.
48. Luridiana A., Pretta G., Chiriu D., Carbonaro C.M., Corpino R., Secci F., Ricci, P.C. A facile strategy for new organic white LED hybrid devices: design, features and engineering // RSC Advances. 2016, Vol. 6, No. 26, pp. 22111Ц-22120.
49. Xiang H.F., Yu S.C., Che C.M., Lai P.T. Efficient white and red light emission from GaN/tris-(8-hydroxyquinolato) aluminum/platinum (II) mesotetrakis (pentafluorophenyl) porphyrin hybrid light-emitting diodes // Appl. Phys. Lett. 2003, Vol. 83, No. 3, pp. 1518Ц1520.
50. Park J.H., Kim J.Y., Chin B.D., Kim Y.C., Kim J.K., Park O.O. White emission from polymer/quantum dot ternary nanocomposites by incomplete energy transfer // Nanotechnology. 2004, Vol. 15, No. 9, pp. 1217Ц1220.
51. Bowers M.J., McBride J.R., Rosenthal S.J. White light emission from magic-sized cadmium selenide nanocrystals // J. Amer. Chem. Soc. 2005, Vol. 127, No. 44, pp. 15378Ц15379.
52. Jang E.P., Song W.S., Lee K.H., Yang H. Preparation of a photo-degradation-resistant quantum dotЦpolymer composite plate for use in the fabrication of a high-stability white-light-emitting diode // Nanotechnology. 2013, Vol. 24, No. 4, 045607.
53. Wang M.S., Guo S.P., Li Y., Cai L.Z., Zou J.P., Xu G., Guo G.C. A direct white-light-emitting metalЦ organic framework with tunable yellow-to-white photoluminescence by variation of excitation light // J. Amer. Chem. Soc. 2009, Vol. 131, No. 38, pp.13572Ц13573.
54. He J., Zeller M., Hunter A.D., Xu Z. White light emission and second harmonic generation from secondary group participation (SGP) in a coordination network // J. Amer. Chem. Soc. 2012, Vol. 134, No. 3, pp. 1553Ц1559.
55. Sava D.F., Rohwer L.E., Rodriguez M.A., Nenoff T.M. Intrinsic broad-band white-light emission by a tuned, corrugated metalЦorganic framework // J. Amer. Chem. Soc. 2012, Vol. 134, No. 9, pp. 3983Ц3986.
56. Sun C.Y., Wang X.L., Zhang X., Qin C., Li P., Su Z.M., Li J. Efficient and tuneable white-light emission of metalЦorganic frameworks by iridium-complex encapsulation // Nature Comm. 2013, 4, AN2717.

Keywords