Content
Abstract:
The structure of a luminous field in a fluorescence layer containing CdSe/CdS/ZnS-based quantum dots and acting as a transducer in an optical fluorescent sensor is described on the basis of three-flux approximation. Differential equation system of three-flux approximation is solved by numerical technique. It is found that diffuse reflectance of the layer extremely depends on concentration of quantum dots in the layer and its physical thickness. Optimal parameters of the layer required for forming of maximum analytical layer are determined.
References:
1. Atkins B. Chemical and Biological Sensors. Moscow: Tekhnosfera, 2005. 2. Bio-sensors: Basics and Applications / Edited by E. Turner, I. Karube and J. Wilson. Moscow: Mir, 1992. 3. Otto M. Contemporary Methods of Analytical Chemistry (in 2 volumes). Moscow: Tekhnosfera, 2004, 416 p. (vol.1), 288 p. (vol. 2). 3. Otto M. Sovremennyie metody analiticheskoi khimii (2 volumes). M: Tekhnosfera, 2004, 416 p. (vol.1), 288 p. (vol. 2). 4. Cordero S.R., Carson P.J., Estabrook R.A., Strouse G.F., Buratto S.K. Photo-Activated Luminescence of CdSe Quantum Dot Monolayers // J. Phys. Chem. B. 2000, Vol. 104, pp. 12137Ц12142. 5. Uematsu T., Maenosono S., Yamaguchi Y. Photoinduced fluorescence enhancement in CdSe/ZnS quantum dot sub-monolayers sandwiched between insulating layers: influence of dot proximity // J. Phys. Chem. B. 2005, Vol. 109, pp. 8613Ц8618. 6. Pechstedt K., Whittle T., Baumberg J., Melvin T. Photoluminescence of colloidal CdSe/ ZnS quantum dots: the critical effect of water molecules // J. Phys. Chem. C. 2010, Vol. 114, No. 28, pp. 12069Ц12077. 7. Ito Y., Matsuda K., Kanemitsu D. Photoluminescence intermittency in single CdSe nanoparticles: environment dependence // J. Lumin. 2008, Vol. 128, No. 5Ц6, pp. 868Ц870. 8. Non-equilibrium processes in sensor structures / Edited by V.A. Smyntyna. Odessa: ONU, 2015. 9. Pavlov S.A., Pavlov A.S., Maksimova E. Yu., Alekseenko A.V., Pavlov A.V., Antipov E.M. Application of CdSe/CdS/ZnS quantum dots in coplaner capacity structures for optical sensors in liquid and gaseous media?3 // Applied Physics. 2018, # 3, pp. 27Ц32. 9. Pavlov S.A., Pavlov A.S., Maksimova E. Yu., Aleksrenko A.V., Pavlov A.V., Antipov E.M. IspolТzovaniie kvantovykh tochek na osnove CdSe/CdS/ZnS v komplanarnykh emkostnylh strukturakh dlia opticheskikh datchikov zhidkikh i gazovykh sredakh. // Prikladnaia fizika. 2018, Issue 3, pp. 27Ц32. 10. Vladimirov Yu.A., Potapenko A. Ya. Physical and chemical basics of photo-biological processes. Moscow: Vysshaya Shkola, 1989, 199 p. 10. Vladimirov Yu.A., Potapenko A. Ya. Fiziko-khimicheskiie osnovy fotobiologicheskikh protsessov. Ц M: Vysshaya Shkola, 1989, 199 p. 11. Pavlov S.A., Pavlov A.S., Maksimova E. Yu., Alekseenko A.V., Pavlov A.V., Antipov E.M. Fluorescent sensor based on CdSe/CdS/ZnS quantum dots for analysis of I2 in gaseuos and water and spirit media // Applied Physics. 2018, Issue 5. 11. Pavlov S.A., Pavlov A.S., Maksimova E. Yu., Alekseenko A.V., Pavlov A.V., Antipov E.M. Liuminiscentnyi sensor na kvantovykh tochkakh CdSe/CdS/ ZnS dlia analiza I2 v gazovykh i vodno-spirtovykh sredakh. // Prikladnaia fizika. 2018, # 5. 12. Gurevich M. Ueber eine Rationelle Klassification der Lichtstreuenden Medien // Physik. Zeitschr, 1930, Bd. 31, pp. 753Ц763. 13. Simonot L., Thoury M., Delaney J. Extension of the KubelkaЦMunk theory for fluorescent turbid media to a nonopaque layer on a background // J. Opt. Soc. Am. A. 2011, Vol. 28, No. 7, pp. 1349Ц1357. 14. Kubelka P., Munk F. Ein Beitrag zur optic der farbanstriche // Z. Techn. Phys. 1931, Bd. 12, # 11a, pp. 593Ц601. 15. Giraev K.V., Ashurbekov N.A., Kobzev O.V. Optical research of bio-tissues: determination of absorption and scattering coefficients// Letters to the Journal of Technical Physics, 2003, Vol.29, #21, pp. 48Ц52. 16. Remisowsky A.M.V., McClendon J.H., Fukhansky L. Estimation of the optical parameters and light gradients in leaves: multi-flux versus two-flux treatment // Photochemistry and Photobiology, 1992, Vol.55, #6, pp. 857-865. 17. Kizel V.A. Light reflection. Moscow: Nauka, 1973, 351 p. 17. Kizel V.A. Otrazheniie sveta. M: Nauka, 1973, 351 p. 18. Shampine L., Gladwell I., Thompson S. Solving ODEs with MATLAB. Saint-Petersburg [and others]: Lan, 2009, 299 p. 19. Sergei A. Pavlov, Sergei L. Koryakin, Natalia E. Sherstenyova, ElenaYu. Maksimova, and Antipov Eugene M. Highly Effective Covering Materials with Quantum Dots for Greenhouses// Light & Engineering Journal, Vol. 26, 2018, #2, pp.36Ц51. 20. Evgeny M. Antipov, Sergey L. Koryakin, Elena Yu. Maksimova, Sergey A. Pavlov, and Sherstnyova Natalya E. Features of the Formation of Radiation Chromaticity by the Dispersion of CdSe/CdS/ZnS Quantum Dots in Multicomponent Systems// Light & Engineering Journal, 2017, Vol. 25, #3, pp.244Ц249.
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